• Atomic Number Of Beryllium
• Atomic Number And Mass Number Worksheet

Learning Objectives

• Define atomic number.
• Define mass number.
• Determine the number of protons, neutrons, and electrons in an atom.

It's important to be able to distinguish atoms of one element from atoms of another element. Elements are pure substances that make up all other matter, so each one is given a unique name. The names of elements are also represented by unique one- or two-letter symbols, such as (ce{H}) for hydrogen, (ce{C}) for carbon, or (ce{He}) for helium. However, it would more powerful if these names could be used to identify the numbers of protons and neutrons in the atoms. That's where atomic number and mass number are useful.

The atomic number of beryllium (Be) is 4, and the atomic number of barium (Ba) is 56. Atomic Number of Elements in Periodic Table. We remember from our school chemistry course that every element has its own specific atomic number. It is the same as the number of protons that the atom of each element has, so sometimes atomic number is called proton number. It is always the whole number and it ranges from 1 to 118, according to.

Atomic Number

Scientists distinguish between different elements by counting the number of protons in the nucleus (Table (PageIndex{1})). If an atom has only one proton, we know that it's a hydrogen atom. An atom with two protons is always a helium atom. If scientists count four protons in an atom, they know it's a beryllium atom. An atom with three protons is a lithium atom, an atom with five protons is a boron atom, an atom with six protons is a carbon atom . . . the list goes on.

Since an atom of one element can be distinguished from an atom of another element by the number of protons in its nucleus, scientists are always interested in this number, and how this number differs between different elements. The number of protons in an atom is called its atomic number ((Z)). This number is very important because it is unique for atoms of a given element. All atoms of an element have the same number of protons, and every element has a different number of protons in its atoms. For example, all helium atoms have two protons, and no other elements have atoms with two protons.

Of course, since neutral atoms have to have one electron for every proton, an element's atomic number also tells you how many electrons are in a neutral atom of that element. For example, hydrogen has an atomic number of 1. This means that an atom of hydrogen has one proton, and, if it's neutral, one electron as well. Gold, on the other hand, has an atomic number of 79, which means that an atom of gold has 79 protons, and, if it's neutral, 79 electrons as well.

Neutral Atoms

Atoms are neutral in electrical charge because they have the same number of negative electrons as positive protons (Table (PageIndex{1})). Therefore, the atomic number of an atom also tells you how many electrons the atom has. This, in turn, determines many of the atom's chemical properties.

Mass Number

The mass number ((A)) of an atom is the total number of protons and neutrons in its nucleus. The mass of the atom is a unit called the atomic mass unit (left( text{amu} right)). One atomic mass unit is the mass of a proton, or about (1.67 times 10^{-27}) kilograms, which is an extremely small mass. A neutron has just a tiny bit more mass than a proton, but its mass is often assumed to be one atomic mass unit as well. Because electrons have virtually no mass, just about all the mass of an atom is in its protons and neutrons. Therefore, the total number of protons and neutrons in an atom determines its mass in atomic mass units (Table (PageIndex{1})).

Consider helium again. Most helium atoms have two neutrons in addition to two protons. Therefore the mass of most helium atoms is 4 atomic mass units ((2 : text{amu}) for the protons + (2 : text{amu}) for the neutrons). However, some helium atoms have more or less than two neutrons. Atoms with the same number of protons but different numbers of neutrons are called isotopes. Because the number of neutrons can vary for a given element, the mass numbers of different atoms of an element may also vary. For example, some helium atoms have three neutrons instead of two (these are called isotopes and are discussed in detail later on).

Why do you think that the 'mass number' includes protons and neutrons, but not electrons? You know that most of the mass of an atom is concentrated in its nucleus. The mass of an atom depends on the number of protons and neutrons. You have already learned that the mass of an electron is very, very small compared to the mass of either a proton or a neutron (like the mass of a penny compared to the mass of a bowling ball). Counting the number of protons and neutrons tells scientists about the total mass of an atom.

[text{mass number} : A = left( text{number of protons} right) + left( text{number of neutrons} right)]

An atom's mass number is very easy to calculate, provided that you know the number of protons and neutrons in an atom.

Example 4.5.1

What is the mass number of an atom of helium that contains 2 neutrons?

Solution

(left( text{number of protons} right) = 2) (Remember that an atom of helium always has 2 protons.)

(left( text{number of neutrons} right) = 2)

(text{mass number} = left( text{number of protons} right) + left( text{number of neutrons} right))

(text{mass number} = 2 + 2 = 4)

A chemical symbol is a one- or two-letter designation of an element. Some examples of chemical symbols are (ce{O}) for oxygen, (ce{Zn}) for zinc, and (ce{Fe}) for iron. The first letter of a symbol is always capitalized. If the symbol contains two letters, the second letter is lower case. The majority of elements have symbols that are based on their English names. However, some of the elements that have been known since ancient times have maintained symbols that are based on their Latin names, as shown in Table (PageIndex{2}).

Summary

• Elements are pure substances that make up all matter, so each one is given a unique name.
• The names of elements are also represented by unique one- or two-letter symbols.
• Each element has a unique number of protons. An element's atomic number is equal to the number of protons in the nuclei of any of its atoms.
• The mass number of an atom is the sum of the protons and neutrons in the atom.
• Isotopes are atoms of the same element (same number of protons) that have different numbers of neutrons in their atomic nuclei.

Contributions & Attributions

This page was constructed from content via the following contributor(s) and edited (topically or extensively) by the LibreTexts development team to meet platform style, presentation, and quality:

• CK-12 Foundation by Sharon Bewick, Richard Parsons, Therese Forsythe, Shonna Robinson, and Jean Dupon.

• Marisa Alviar-Agnew (Sacramento City College)

• Henry Agnew (UC Davis)

Learning Outcomes

• Define atomic and mass numbers.
• Determine the number of protons, neutrons, and electrons in an atom.
• Identify the charge and relative mass of subatomic particles.
• Label the location of subatomic particles in the atom.
• Determine the mass of an atom based on its subatomic particles.
• Write A/Z and symbol-mass format for an atom.

Atoms are the fundamental building blocks of all matter and are composed of protons, neutrons, and electrons. Because atoms are electrically neutral, the number of positively charged protons must be equal to the number of negatively charged electrons. Since neutrons do not affect the charge, the number of neutrons is not dependent on the number of protons and will vary even among atoms of the same element.

Atomic Number

The atomic number (represented by the letter Z)of an element is the number of protons in the nucleus of each atom of that element. An atom can be classified as a particular element based solely on its atomic number. For example, any atom with an atomic number of 8 (its nucleus contains 8 protons) is an oxygen atom, and any atom with a different number of protons would be a different element. The periodic table (see figure below) displays all of the known elements and is arranged in order of increasing atomic number. In this table, an element's atomic number is indicated above the elemental symbol. Hydrogen, at the upper left of the table, has an atomic number of 1. Every hydrogen atom has one proton in its nucleus. Next on the table is helium, whose atoms have two protons in the nucleus. Lithium atoms have three protons, beryllium atoms have four, and so on.

Since atoms are neutral, the number of electrons in an atom is equal to the number of protons. Hydrogen atoms all have one electron occupying the space outside of the nucleus. Helium, with two protons, will have two electrons. In the chemical classroom, the proton count will always be equivalent to an atom's atomic number. This value will not change unless the nucleus decays or is bombarded (nuclear physics).

Mass Number

Experimental data showed that the vast majority of the mass of an atom is concentrated in its nucleus, which is composed of protons and neutrons. The mass number (represented by the letter A)is defined as the total number of protons and neutrons in an atom. Consider the table below, which shows data from the first six elements of the periodic table.

Consider the element helium. Its atomic number is 2, so it has two protons in its nucleus. Its nucleus also contains two neutrons. Since (2 + 2 = 4), we know that the mass number of the helium atom is 4. Finally, the helium atom also contains two electrons, since the number of electrons must equal the number of protons. This example may lead you to believe that atoms have the same number of protons and neutrons, but a further examination of the table above will show that this is not the case. Lithium, for example, has three protons and four neutrons, giving it a mass number of 7.

Knowing the mass number and the atomic number of an atom allows you to determine the number of neutrons present in that atom by subtraction.

[text{Number of neutrons} = text{ rounded mass number} - text{atomic number}]

Atoms of the element chromium (left( ce{Cr} right)) have an atomic number of 24 and a mass number of 52. How many neutrons are in the nucleus of a chromium atom? To determine this, you would subtract as shown:

[52 - 24 = 28 : text{neutrons in a chromium atom}]

The composition of any atom can be illustrated with a shorthand notation called A/Z format. Both the atomic number and mass are written to the left of the chemical symbol. The 'A' value is written as a superscript while the 'Z' value is written as a subscript. For an example of this notation, look to the chromium atom shown below:

[ce{^{52}_{24}Cr}]

Another way to refer to a specific atom is to write the mass number of the atom after the name, separated by a hyphen. Symbol-mass format for the above atom would be written as Cr-52. In this notation, the atomic number is not included. You will need to refer to a periodic table for proton values.

Example (PageIndex{1})

Calculate each of the three subatomic particles and give specific group or period names for each atom.

1. mercury
2. platinum
3. bromine

Solutions

1. Hg (transition metal)- has 80 electrons, 80 protons, and 121 neutrons
2. Pt (transition metal)- has 78 electrons, 78 protons, and 117 neutrons
3. Br (halogen)- has 35 electrons, 35 protons, and 45 neutrons

Example (PageIndex{2})

Write both A/Z and symbol-mass formats for the atoms in Example (PageIndex{1}).

Solutions

1. (ce{^{201}_{80}Hg}) and Hg-201
2. (ce{^{195}_{78}Pt}) and Pt-195
3. (ce{^{80}_{35}Br}) and Br-80

Example (PageIndex{3})

Atomic Number Of Beryllium

Identify the elements based on the statements below.

1. Which element has 25 protons?
2. Which element has 0 neutrons?
3. Which element has 83 electrons?

Solutions

a. manganese

b. hydrogen

c. bismuth

Need More Practice?

• Turn to section 3.E of this OER and answer questions #1-#2, #4, and #8.

Contributors and Attributions

Atomic Number And Mass Number Worksheet

• CK-12 Foundation by Sharon Bewick, Richard Parsons, Therese Forsythe, Shonna Robinson, and Jean Dupon.

• Allison Soult, Ph.D. (Department of Chemistry, University of Kentucky)